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2 edition of Studies on the synthesis of six-membered nitrogen heterocyclic compounds. found in the catalog.

Studies on the synthesis of six-membered nitrogen heterocyclic compounds.

Stephen P. Brown

Studies on the synthesis of six-membered nitrogen heterocyclic compounds.

by Stephen P. Brown

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Published by University of East Anglia in Norwich .
Written in English


Edition Notes

Thesis (Ph.D.), University of East Anglia, School of Chemical Sciences, 1984.

ID Numbers
Open LibraryOL20931645M

General aspects of heterocyclic compounds. The most common heterocycles are those having five- or six-membered rings and containing heteroatoms of nitrogen (N), oxygen (O), or sulfur (S). The best known of the simple heterocyclic compounds are pyridine, pyrrole, furan, and thiophene.   The Chemistry of Heterocyclic Compounds, since its inception, has been recognized as a cornerstone of heterocyclic chemistry. Each volume attempts to discuss all aspects properties, synthesis, reactions, physiological and industrial significance of a specific ring system. To keep the series up-to-date, supplementary volumes covering the recent literature Author: Adolfo Quilico.

Six-membered heterocyclic nitrogen compounds with four condensed rings (The chemistry of heterocyclic compounds) [C.F.H. Allen] on *FREE* shipping on qualifying offers. This book is a compilation of the recent applications of palladium catalysts in organic synthesis. The book demonstrates that it is a highly dynamic research field. This methodology has emerged as a powerful tool for the efficient and chemoselective synthesis .

A palladium-catalyzed cyclization reaction for the modular synthesis of highly substituted piperazines and related bis-nitrogen heterocycles couples two of the carbons of a propargyl unit with various diamine components to provide products in very good yields with high regio- and stereochemical control. The alkylation of β-dicarbonyl compounds in a K2CO3/DMSO system wasfound to afford O- and C-alkylated derivatives, depending on the type of the β-dicarbonylcompound involved. The alkyl derivatives obtained were used in the synthesis of some newspiro barbituric acid derivatives. Quantum chemical calculations were carried out toelucidate the reaction mechanisms for Cited by: 1.


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Studies on the synthesis of six-membered nitrogen heterocyclic compounds by Stephen P. Brown Download PDF EPUB FB2

Alternatively, the direct one-pot generation of fused nitrogen heterocyclic systems from the nitrogen framework of 2-azetidinone derivatives has been achieved by. Shafiquzzaman Siddiquee, in Biotechnology and Biology of Trichoderma, Nitrogen Heterocyclic Compounds. Heterocyclic compounds are cyclic compounds with the ring containing carbon and other element, the component being oxygen, nitrogen and sulfur.

The simplest of the five membered heterocyclic compounds are pyrrole, furan and thiophene, each of which. For nitrogen, such heterocyclic compounds are possible with the retention of a three-coordinate neutral, or four-coordinate positively charged, nitrogen atom. The chapter successively considers the formation of small (three- or four-membered) rings with one N at a ring junction, five-membered and then six-membered rings with one ring junction N.

A heterocyclic compound or ring structure is a cyclic compound that has atoms of at least two different elements as members of its ring(s).

Heterocyclic chemistry is the branch of organic chemistry dealing with the synthesis, properties, and applications of these heterocycles. Examples of heterocyclic compounds include all of the nucleic acids, the majority of drugs.

An overview of the application of microwave irradiation in nitrogen-containing fused six-membered heterocyclic compounds synthesis is presented, focusing on the developments in. SOME STUDIES IN NITROGEN HETEROCYCLIC CHEMISTRY USING REISSERT COMPOUNDS by Yee-Ping Ho,G.R.S.C.

A Doctoral Thesis Submitted in partial fulfilment of the requirements for the award of DOCTOR OF PHILOSOPHY of LOUGHBOROUGH UNIVERSITY OF TECHNOLOGY October Supervisor: Dr. B.C. Uff,Rh.D. Figure Examples of heterocyclic compounds. Table Main three- and four-membered heterocycles.

Ring size Heteroatom N O S Other 3 N H Aziridine O Oxirane S Thiirane N H NH Diaziridine O O Dioxirane O NH Oxaziridine 4 NH Azetidine O Oxetane S Thietane Se P R Seletane Phosphetane 2j 1 Heterocyclic Compounds: An IntroductionFile Size: KB. In this review paper, information about heterocyclic compounds, methods of synthesis, reactions, properties, stability, saturated and unsaturated cycles, aliphatic and aromatic cycles have been thoroughly reviewed and discussed.

KEYWORDS: Heterocyclic, Three Membered, Seven, Cyclization, Sulfur,Nitrogen INTRODUCTION Three Membered RingsFile Size: KB. •Synthesis of the GSK p38 kinase inhibitor 1,3‐Azoles Synthesis of 2-Butylchlorohydroxymethyl-1H-imidazole H N N CH3 HO H2N HN CH3 HO O OH Cl HN N N N N CH3 H2N HN CH3 H N N CH3 HO H N CH3 HO HO O OH + 1.

Me3SiCl, succinimide 3. Zn, AcOH NH3,MeOH Cl HO N Cl Losartan N Cl Synthetic Communications (), 23(18), 2 File Size: 1MB. This review describes the formation of six-membered heterocyclic compounds and their fused analogues under microwave activation using modern organic transformations including cyclocondensation, cycloaddition, multicomponents and other modular reactions.

The review is divided according to the main heterocycle types in order of increasing complexity, starting with Cited by: Volume 3 of Comprehensive Heterocyclic Chemistry: The Structure, Reactions, Synthesis, and Uses of Heterocyclic Compounds.

Part 2B. Six-membered Rings with Oxygen, Sulfur Or Two Or More Nitrogen Atoms, Alan R. Katritzky, ISBNHeterocyclic compounds are organic compounds containing at least one atom of carbon, and at least one element other than carbon, such as sulphur, oxygen or nitrogen within a ring structure.

These structures may comprise either simple aromatic rings or non-aromatic rings. Some examples are pyridine (C5H5N), pyrimidine (C4H4N2) and dioxane (C4H8O2). SOLOMON DERESE Ph.D (Chemistry)University of Nairobi, Kenya.

(Chemistry) Department of Chemistry, University of Nairobi, P.O. Box INTRODUCTION: Any of a major class of organic chemical compounds characterized by the fact that some or all of the atoms in their molecules are joined in rings containing at least one atom of an element other than cyclic part of heterocyclic indicates that at least one ring structure is present in such a compound, while the prefix hetero refers to the noncarbon.

Keywords:Ring closing metathesis, synthesis of heterocycles, Grubbs 'catalyst, oxygen heterocycles, nitrogen heterocycles. Abstract: This brief review article describes the progress made in the synthesis of five- and six-membered heterocyclic rings by the application of the ring-closing metathesis reactions during the period of Cited by: The ring closing metathesis on appropriate vinyl or allyl aminoboranes (1 or 2) gives azaboracycloalkenes (3 or 4) which can be converted to azaborolides (5) or azaborines (6).

A Synthesis of Aromatic Five- and Six-Membered B−N Heterocycles via Ring Closing Metathesis - Organic Letters (ACS Publications)Cited by: Cycloisomerization of 1,n-enynes and diynes is a powerful method in organic synthesis to access heterocyclic compounds and has drawn increasing attention from organic chemists.

In this paper, we attempted to summarize our recent results on the transition metal-catalyzed cycloisomerization to synthesize five or six-membered heterocyclic compounds using 1,n-enynes and diynes Cited by: Erich Kleinpeter, Conformational Analysis of Saturated Six-Membered Oxygen-Containing Heterocyclic Rings, /S(08), (), ().

Crossref Hanoch Senderowitz and Benzion Fuchs, Steric and stereoelectronic effects in saturated heterocycles I. Small molecular fragment by: A unique cyclization of benzamide derivatives that contain a propargyl ether by a Pd(0)/dialkyl(biaryl)phosphine catalytic system efficiently provides various six-membered N-heterocyclic compounds that contain a fully substituted carbon center.

Mechanistic studies suggest that this unprecedented cyclization starts with the cleavage of a. Five and six-membered nitrogen-containing heterocycles.

Synthesis and applications 6 II. Synthesis, characterisation and biological evaluation of some new triazin-triazoles derivatives II Synthesis strategies The synthetic way adopted for obtaining the target hybrid compounds starts with 1,3,5-triazine.

Five elegant and switchable three-component reactions which enable access to a new series of nitrogen-containing heterocycles are reported.

A novel one-step addition of an isocyanide to a hydrazine derived Schiff base affords unique six-membered pyridotriazine scaffolds (A and E). With slight modification of reaction conditions and replacement of the nucleophilic isocyanide Cited by: Seven-membered heterocyclic compounds containing oxygen and sulfur.

(The Chemistry of heterocyclic compounds, v. 26) Includes bibliographical references. 1. Oxepins. 2. Thiepins. I. Title. QDR68 ' ISBN The purpose of this review is to present a systematic survey of the most recent literature that uses chalcones in the synthesis of biologically active 5- and 6-membered nitrogen heterocycles such as pyrroles, indoles, isoxazoles, imidazoles, pyrazoles, Cited by: